Chemistry-Study and teaching; Handouts; Thermodynamics; Second law of thermodynamics; Chemical equilibrium
Introduction: The First Law of Thermodynamics places important restraints on the path that can be taken by a system but it does not define the path. For example, the First Law does not rule out the possibility of warming oneself by sitting on a...
Chemistry-Study and teaching; Handouts; Valence (Theoretical chemistry); Chemical bonds; Electrons; Molecular orbitals
In class, we have used the Valence Bond (VB) approach to understand chemical
bonding. At the qualitative level, VB is relatively easy to use and does not require a deep
knowledge of quantum mechanics and group theory. The electron-dot formalism of...
Chemistry-Study and teaching; Atomic structure; Molecular structure; Examinations; Atomic orbitals; Questions and answers; Lewis dot structures; Chemical bonds
Questions and answers for the third midterm examination of Fall 1999, involving six multi-step problems covering atomic and molecular structure.
Chemistry-Study and teaching; Homework; Molecular orbitals; Chemical bonds
Introduction: In class we applied molecular orbital theory to a few simple examples with the goal of understanding the nature of the chemical bond. The qualitative approach is complemented by numerical calculations and the interpretation of these...
Chemistry-Study and teaching; Homework; Problem solving
Introduction: Use the approach outlined in the handout "How To Solve Equilibrium Problems" to solve the following problems related to the hydrogenation reaction. Use partial pressure as the concentration unit for the gaseous species.
Chemistry-Study and teaching; Thermodynamics; Electrochemistry; Questions and answers; Examinations; First law of thermodynamics; Second law of thermodynamics
Questions and answers for the second midterm examination of Fall 1999, involving five multi-step problems covering chemical thermodynamics.
Handout from the laboratory manual explaining curve fitting and the method of least squares. Included is a least squares exercise using Microsoft Excel.
Chemistry-Study and teaching; Handouts; Chemical kinetics; Chemical reactions; Solution (Chemistry)
Experiment with the objective of determining the rate law for the reaction between the dichromate ion and the acetaldehyde molecule in a dilute solution of nitric acid.
Chemistry-Study and teaching; Handouts; Quantum theory; Eigenfunctions; Perturbation (Quantum dynamics)
Handout on perturbation theory in quantum mechanics written by the instructor as a supplement to the textbook. It looks at an approach for the case where a problem differs slightly from one that can be solved exactly.
Chemistry-Study and teaching; Adsorption; Molecular sieves; Gases
Experiment involving studying the adsorption of gaseous nitrogen and dimethyl ether on a molecular sieve; it also provides experience with manipulations on a vacuum line.
Chemistry-Study and teaching; Molecular spectroscopy; Thermodynamics; Gases
Experiment previously used in the course, meant to introduce the student to molecular spectroscopy and to the molecular parameters and thermodynamic properties which can be obtained by analyzing the vibration-rotation spectrum of gaseous hydrogen...
Chemistry-Study and teaching; Handouts; Thermodynamics; First law of thermodynamics; Chemical equilibrium
Introduction. The purpose of this short discussion is to provide a correct yet understandable introduction to thermodynamics. It is intended to replace and not complement the material in your text. The author is schooled in the Oberlin school of...
