Chemistry-Study and teaching; Molecular rotation; Spectroscopy, Nuclear magnetic resonance; Chemical kinetics
Experiment involving learning how kinetic information can be obtained from an NMR line shape and determining the activation parameters for internal rotation of the N,N-dimethylamino group in N,N-dimethylacetamide.
Chemistry-Study and teaching; Homework; Molecular orbitals; Chemical bonds
Introduction: In class we applied molecular orbital theory to a few simple examples with the goal of understanding the nature of the chemical bond. The qualitative approach is complemented by numerical calculations and the interpretation of these...
Chemistry-Study and teaching; Handouts; Thermodynamics; First law of thermodynamics; Chemical equilibrium
Introduction. The purpose of this short discussion is to provide a correct yet understandable introduction to thermodynamics. It is intended to replace and not complement the material in your text. The author is schooled in the Oberlin school of...
Chemistry-Study and teaching; Voltammetry; Electrochemistry; Solution (Chemistry)
Experiment with the goal of gaining an understanding of anodic stripping voltammetry and an understanding of the factors involved in performing quantitative analytical determinations, through the determinations of amounts of copper.
Chemistry-Study and teaching; Handouts; Valence (Theoretical chemistry); Chemical bonds; Electrons; Molecular orbitals
In class, we have used the Valence Bond (VB) approach to understand chemical
bonding. At the qualitative level, VB is relatively easy to use and does not require a deep
knowledge of quantum mechanics and group theory. The electron-dot formalism of...
Chemistry-Study and teaching; Absorption spectra; Molecular spectroscopy; Thermodynamics; Statistical mechanics
Experiment involving an introduction to molecular spectroscopy and the extraction of molecular parameters and thermodynamic properties from an analysis of the vibrational fine structure of an electronic band spectrum of gaseous iodine.
Chemistry-Study and teaching; Handouts; Homework; Crystals; Solvents; Solution (Chemistry); Electrons
Experiment with the objective of synthesizing an inorganic complex compound in pure form and high yield and of discovering the chemistry involved in the syntheses. Determining the compound's paramagnetic susceptibility is involved.
Chemistry-Study and teaching; Spectroscopy, Nuclear magnetic resonance;
Experiment designed to introduce the fundamental principles and practice of magnetic resonance imaging (MRI), a form of NMR spectroscopy, by obtaining and examining a two-dimensional image of the stem or bud from a plant.