Chemistry-Study and teaching; Handouts; Thermodynamics; First law of thermodynamics; Chemical equilibrium
Introduction. The purpose of this short discussion is to provide a correct yet understandable introduction to thermodynamics. It is intended to replace and not complement the material in your text. The author is schooled in the Oberlin school of...
Chemistry-Study and teaching; Handouts; Thermodynamics; Second law of thermodynamics; Chemical equilibrium
Introduction: The First Law of Thermodynamics places important restraints on the path that can be taken by a system but it does not define the path. For example, the First Law does not rule out the possibility of warming oneself by sitting on a...
Chemistry-Study and teaching; Spectroscopy, Nuclear magnetic resonance;
Experiment designed to introduce the fundamental principles and practice of magnetic resonance imaging (MRI), a form of NMR spectroscopy, by obtaining and examining a two-dimensional image of the stem or bud from a plant.
Handout explaining systematic and random errors, precision versus accuracy, significant figures, absolute and relative error, propagation of errors, measurement distribution, etc.
Chemistry-Study and teaching; Homework; Molecular structure; Molecules-Models; Quantum chemistry; Electrons--Diffraction
This is the Molecular Zoo entry for furan and therefore describes the detailed three-dimensional, gas-phase structure of furan produced by instrumental and computational methods. It also offers a critical comparison of these various experimental...
Chemistry-Study and teaching; Chemical bonds; Transition metals; Molecular orbitals
Introduction. The purpose of this handout is to provide a simple model for the bonding in transition-metal complexes as a framework for understanding and interpreting the most important properties of these complexes. We shall deal mostly with the...
Chemistry-Study and teaching; Homework; Molecular structure; Molecules-Models
This is the Molecular Zoo entry for aniline and therefore describes the detailed three-dimensional, gas-phase structure of aniline produced by instrumental and computational methods. It also offers a critical comparison of these various...
Chemistry-Study and teaching; Handouts; Solution (Chemistry)
Experiment in which the objective is to separate, by gas chromatographic techniques, a mixture of the four isomeric butyl alcohols and to determine the percentage of each an unknown mixture.
Chemistry-Study and teaching; Voltammetry; Electrochemistry; Solution (Chemistry)
Experiment with the goal of gaining an understanding of anodic stripping voltammetry and an understanding of the factors involved in performing quantitative analytical determinations, through the determinations of amounts of copper.
Chemistry-Study and teaching; Handouts; Molecules; Conformational analysis
Description of how to use the software involved in many of the exercises for Chemistry 164, focusing on answers to frequently asked questions on how to search for conformers in the program Spartan along with a help file from Wavefunction.
Chemistry-Study and teaching; Handouts; Valence (Theoretical chemistry); Chemical bonds; Electrons; Molecular orbitals
In class, we have used the Valence Bond (VB) approach to understand chemical
bonding. At the qualitative level, VB is relatively easy to use and does not require a deep
knowledge of quantum mechanics and group theory. The electron-dot formalism of...
Chemistry-Study and teaching; Molecules-Models; Lewis dot structures; Molecular structure
Experiment designed to acquaint a student with selected but instructive techniques of molecular modeling. It involves using computational methods to answer chemical questions.
Chemistry-Study and teaching; Homework; Chemical kinetics; Chemical reactions
Exercise dealing with rate laws and mechanisms, using a special computer program to simulate an experiment. The exercise focuses on the experimental design and an analysis of the results.
Chemistry-Study and teaching; Molecular rotation; Spectroscopy, Nuclear magnetic resonance; Chemical kinetics
Experiment involving learning how kinetic information can be obtained from an NMR line shape and determining the activation parameters for internal rotation of the N,N-dimethylamino group in N,N-dimethylacetamide.
Chemistry-Study and teaching; Adsorption; Molecular sieves; Gases
Experiment involving studying the adsorption of gaseous nitrogen and dimethyl ether on a molecular sieve; it also provides experience with manipulations on a vacuum line.
