Chemistry-Study and teaching; Voltammetry; Electrochemistry; Solution (Chemistry)
Experiment with the goal of gaining an understanding of anodic stripping voltammetry and an understanding of the factors involved in performing quantitative analytical determinations, through the determinations of amounts of copper.
Handout from the laboratory manual explaining curve fitting and the method of least squares. Included is a least squares exercise using Microsoft Excel.
Chemistry-Study and teaching; Gas chromatography; Mass spectrometry
Experiment involving the isolation, concentration, separation and identification of the volatile components of a foodstuff (via headspace analysis, capillary gas chromatography, and mass spectra measurements).
Chemistry-Study and teaching; Molecular spectroscopy; Thermodynamics; Gases
Experiment previously used in the course, meant to introduce the student to molecular spectroscopy and to the molecular parameters and thermodynamic properties which can be obtained by analyzing the vibration-rotation spectrum of gaseous hydrogen...
Chemistry-Study and teaching; Solution (Chemistry); High performance liquid chromatography
Experiment with purpose of quantifying the caffeine content of a diet cola sample using high performance liquid chromatography. The separation of components in diet soft drinks is also involved.
Chemistry-Study and teaching; Molecular rotation; Spectroscopy, Nuclear magnetic resonance; Chemical kinetics
Experiment involving learning how kinetic information can be obtained from an NMR line shape and determining the activation parameters for internal rotation of the N,N-dimethylamino group in N,N-dimethylacetamide.
An annotated bibliography for Analytical Chemistry, with links to sources of chemical data on the World Wide Web involving instrumental analysis, techniques, chemometrics and data analysis.
Chemistry-Study and teaching; Absorption spectra; Molecular spectroscopy; Thermodynamics; Statistical mechanics
Experiment involving an introduction to molecular spectroscopy and the extraction of molecular parameters and thermodynamic properties from an analysis of the vibrational fine structure of an electronic band spectrum of gaseous iodine.
Chemistry-Study and teaching; Handouts; Solution (Chemistry)
Experiment in which the objective is to separate, by gas chromatographic techniques, a mixture of the four isomeric butyl alcohols and to determine the percentage of each an unknown mixture.
Chemistry-Study and teaching; Spectroscopy, Nuclear magnetic resonance
Experiment previously used in the course and focused on selective irradiation and nuclear magnetic resonance (NMR), specifically involving homonuclear decoupling and the NOE (nuclear Overhauser enhancement) difference experiment.
Chemistry-Study and teaching; Handouts; Molecules; Conformational analysis
Description of how to use the software involved in many of the exercises for Chemistry 164, focusing on answers to frequently asked questions on how to search for conformers in the program Spartan along with a help file from Wavefunction.
Chemistry-Study and teaching; Handouts; Thermodynamics; First law of thermodynamics; Chemical equilibrium
Introduction. The purpose of this short discussion is to provide a correct yet understandable introduction to thermodynamics. It is intended to replace and not complement the material in your text. The author is schooled in the Oberlin school of...
Experiment in which the objectives are to determine the percentage copper in a brass sample from the amount of radioactivity that has been produced by bombardment with a beam of neutrons and to determine the half-life of an isotope from the rate at...